Crystal structure of {2,6-bis[(dimethylamino)methyl]phenyl-κ3 N,C 1,N′}(bromido/chlorido)mercury(II)
نویسندگان
چکیده
In the mol-ecular structure of the title compound, {2,6-bis-[(di-methyl-amino)-meth-yl]phenyl-κ3N,C1,N'}[bromido/chlorido-(0.30/0.70)]mercury(II)-{2,6-bis-[(di-methyl-amino)-meth-yl]phenyl-κ3N,C1,N'}[bromido/chlorido-(0.24/0.76)]mer-cury(II) (1/1), [HgBr0.30Cl0.70(C12H19N2)]·[HgBr0.24Cl0.76(C12H19N2)], there are two mol-ecules in the asymmetric unit of formula LHgX {L = 2,6-bis-[(di-methyl-amino)-meth-yl]phenyl and X = Cl/Br}. In each mol-ecule, the halide site is mixed Cl/Br, with occupancies of 0.699 (7):0.301 (7) and 0.763 (7):0.237 (7), respectively. The two mol-ecules are linked into dimers by a combination of Hg⋯Hg [Hg⋯Hg = 3.6153 (3) Å] and C-H⋯Cl and C-H⋯π inter-actions.
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عنوان ژورنال:
دوره 73 شماره
صفحات -
تاریخ انتشار 2017